The conference will take place at complex "Convento San Pedro Mártir y Madre de Dios" (A1 in the map), which was a Dominican monastery nowadays refurbished by Universidad de Castilla - La Mancha. Here is a map of Toledo with indication of UCLM buildings.
Toledo is a very easy city to get around, although the streets can be a little bit like a maze at times. The centre is fairly compact and most of the places are within walking distance of one another. It is strongly advisible not use your car inside the centre.